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Metal–ligand cooperativity enables zero-valent metal transfer

https://doi.org/10.1039/D4SC07938H

Riu, Martin-Louis Y; Shan, Jing-Ran; Houk, K N; Nava, Matthew (February 2025, Chemical Science)

Group 13 aminoxy complexes, (L)E(TEMPO)₃(TEMPO = 2,2,6,6-tetramethylpiperidine 1-oxyl; L = THF (tetrahydrofuran) or Py (pyridine); E = Al, Ga, In), display ambiphilic reactivity with H₂and function as synthons for the preparation of materials.
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Free, publicly-accessible full text available February 26, 2026
Synthesis of [Os(bpy) ₂ (py)(OH ₂ )](PF ₆ ) _x substituted pyridine complexes; characterization of a singly bridged H ₃ O ₂ ⁻ ligand

https://doi.org/10.1039/D5DT00419E

Sun, Jiangtian; Sun, Jingwen; Jolly, Brandon J; Riu, Martin-Louis Y; Kerr, Tyler A; Lai, Yi-An; Pung, Michael J; Liu, Chong; Nava, Matthew (March 2025, Dalton Transactions)

In situelectrochemical analysis enables access to metal aquo PCET model complexes which are synthetically elaborated and speciation was determined.
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Free, publicly-accessible full text available March 17, 2026
Introducing N -Heterocyclic Iminophosphoranes (NHIPs): Synthesis by [3 + 2] Cycloaddition of Azophosphines with Alkynes and Reactivity Studies

https://doi.org/10.1021/acs.inorgchem.2c01844

Tanaka, Keita; Riu, Martin-Louis Y.; Valladares, Brian; Cummins, Christopher C. (September 2022, Inorganic Chemistry)

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Reactions of Tri- tert -Butylphosphatetrahedrane as a Spring-Loaded Phosphinidene Synthon Featuring Nickel-Catalyzed Transfer to Unactivated Alkenes

https://doi.org/10.1021/jacs.2c02236

Riu, Martin-Louis Y.; Eckhardt, André K.; Cummins, Christopher C. (May 2022, Journal of the American Chemical Society)

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Taming phosphorus mononitride

https://doi.org/10.1038/s41557-022-00958-5

Eckhardt, André K.; Riu, Martin-Louis Y.; Ye, Mengshan; Müller, Peter; Bistoni, Giovanni; Cummins, Christopher C. (August 2022, Nature Chemistry)

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Staudinger Reactivity and Click Chemistry of Anthracene ( A )-Based Azidophosphine N ₃ P A

https://doi.org/10.1021/acs.inorgchem.1c03753

Eckhardt, André K.; Riu, Martin-Louis Y.; Müller, Peter; Cummins, Christopher C. (January 2022, Inorganic Chemistry)

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Alleviating Strain in Organic Molecules by Incorporation of Phosphorus: Synthesis of Triphosphatetrahedrane

https://doi.org/10.1021/jacs.1c07959

Riu, Martin-Louis Y.; Ye, Mengshan; Cummins, Christopher C. (October 2021, Journal of the American Chemical Society)
null (Ed.)
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Frustrated Lewis Pair Stabilized Phosphoryl Nitride (NPO), a Monophosphorus Analogue of Nitrous Oxide (N ₂ O)

https://doi.org/10.1021/jacs.1c11426

Eckhardt, André K.; Riu, Martin-Louis Y.; Müller, Peter; Cummins, Christopher C. (December 2021, Journal of the American Chemical Society)

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Dimerization and Cycloaddition Reactions of Transient Tri- tert -butylphosphacyclobutadiene Generated by Lewis Acid Induced Isomerization of Tri- tert -butylphosphatetrahedrane

https://doi.org/10.1021/jacs.1c06840

Riu, Martin-Louis Y.; Eckhardt, André K.; Cummins, Christopher C. (August 2021, Journal of the American Chemical Society)
null (Ed.)
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Understanding the Nature and Properties of Hydrogen–Hydrogen Bonds: The Stability of a Bulky Phosphatetrahedrane as a Case Study

https://doi.org/10.1021/acs.jpca.1c04046

Riu, Martin-Louis Y.; Bistoni, Giovanni; Cummins, Christopher C. (July 2021, The Journal of Physical Chemistry A)
null (Ed.)
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